Enhanced Electrochemical Performance of Mn3O4/Multiwalled Carbon Nanotube Nanocomposite for Supercapacitor Applications

Abirami, R. and Kabilan, R. and Nagaraju, P. and Hariharan, V. and Thennarasu, S. (2021) Enhanced Electrochemical Performance of Mn3O4/Multiwalled Carbon Nanotube Nanocomposite for Supercapacitor Applications. JOURNAL OF ELECTRONIC MATERIALS, 50.0 (11). pp. 6467-6474. ISSN 0361-5235

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Abstract

Mn3O4/multiwalled carbon nanotube (MWCNT) nanocomposites were synthesized via a facile ultrasonic method, using manganese chloride as a precursor at room temperature for supercapacitor applications. The nanocomposites were characterized by powder x-ray diffraction (XRD), transmission electron microscopy (TEM) and field emission scanning electron microscopy (FE-SEM), respectively. TEM images revealed that the Mn3O4 nanoparticles were highly dispersed on the surface of the MWCNT. Cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS) were performed for the Mn3O4/MWCNT nanocomposites using 1 M Na2SO4 aqueous solutions as the electrolyte in order to find the suitability of the material for supercapacitor applications. The electrochemical results exhibit improved performance for the Mn3O4/MWCNT composite electrode compared to pristine Mn3O4 nanoparticles owing to its structural superiority. The specific capacitance (C-s) of Mn3O4/MWCNT nanocomposites and pristine Mn3O4 was about 473 F g(-1) and 259 F g(-1) , respectively, at a current density of 1 A g(-1). The Mn3O4/MWCNT composite sustains a very strong cyclic performance after 5000 cycles. The capacitance retention of the composite electrode shows highly stable performance confirming its suitability as lasting electrode material for supercapacitor applications.

Item Type: Article
Uncontrolled Keywords: Mn3O4, nanocomposites, specific capacitance, supercapacitor, current density
Subjects: Engineering > Engineering
Material Science > Materials Science
Multi-Disciplinary Studies > Multidisciplinary
Physics and Astronomy > Physics
Divisions:
Depositing User: Unnamed user with email techsupport@mosys.org
Last Modified: 06 Feb 2026 07:13
URI: https://ir.vmrfdu.edu.in/id/eprint/7106

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