Kavitha, R. and Annalakshmi, R. (2008) Kinetics of polymerization of acrylamide and methylacrylate initiated by Mn3+-3-ketoglutaric acid redox system. ASIAN JOURNAL OF CHEMISTRY, 20.0 (2). pp. 1231-1237. ISSN 0970-7077
Full text not available from this repository.Abstract
The kinetics of two vinyl monomers acrylamide and methylacrylate by using redox system Mn3+-ketoglutaric acid at 20 degrees C has been investigated. The result indicates that the methylacrylate has higher monomer reactivity than acrylamide with respect to each of ketoglutaric acid, Mn(III) and H+. Negligible effect of ionic strength variations on reaction rate was observed. The rate of polymerization has a first order dependence on concentration of monomers was observed. A suitable mechanism with kinetic results has been proposed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | kinetics, Mn(III) acetate, excellent initiator of free radical polymerization, acrylamide, methylacrylate, ketoglutaric acid |
| Depositing User: | Unnamed user with email techsupport@mosys.org |
| Last Modified: | 06 Feb 2026 06:51 |
| URI: | https://ir.vmrfdu.edu.in/id/eprint/6149 |
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